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Dioxins
Dioxins are unwanted by-products produced by both industrial processes
and natural events, such as forest fires and incomplete combustion.
Levels of dioxins in the Canadian environment have decreased significantly
over the last several years.
According to Environment Canada's Draft Second Edition June 2000
report, "Dioxins and Furans and Hexachlorobenzene Inventory"1,
emissions of dioxins to air, water and soil have decreased from
an estimated 1,043 grams/year TEQ in 1990 to an estimated 378 grams/year
TEQ in 1999 - a reduction of 64%. The inventory is available on
line at Environment Canada's website http://www.ec.gc.ca.
To ensure further reductions, a multistakeholder process is currently
underway to develop Canada-Wide Standards for emissions of dioxins/furans.
In June 2000, the Canadian Council of Ministers of the Environment
proposed a new Canada-wide standard for incinerators to 0.08 nanograms/cubic
metre by 2006.
The top sources of dioxin emissions to air listed in the above
inventory1 are:
- Conical Burners - 75 grams/year TEQ
- Waste Incineration - 41 grams/year TEQ
- Medical - 25 grams/year TEQ
- Municipal - 9 grams/year TEQ
- Hazardous - 7 grams/year TEQ
- Residential wood combustion - 19 grams/year TEQ
- Steel Manufacturing - Electric Arc Furnaces- 14 grams/year
TEQ
- Pulp & Paper- Burning salt-laden wood - 8 grams/year
TEQ
- Iron Manufacturing - Sintering Plants - 6 grams/year TEQ
Several studies have shown there is no significant relationship
between the amount of chlorine in incinerator feeds and the dioxin
emissions from waste incinerators - it is an issue of combustion
efficiency. Better combustion practices, having the Best Available
Techniques installed on incinerators, have the biggest effect on
further reducing dioxin emissions.2
1. The inventory is available
on line at Environment Canada's website http://www.ec.gc.ca.
2. American Society of Mechanical
Engineers. 1995. The Relationship Between Chlorine in the Waste
Streams and Dioxin Emissions from Waste Combustor Stacks. CRTD Vol.
36.
Wikstrom, E., Marklund, S. 1998. The influence of level and chlorine
source on the formation of PCDD and PCDF during MSW combustion.
Organohalogen Compounds 36: 347.
Yennie, C.R. 1997. Methods to Reduce HCl Emissions in a Medical
Waste Incinerator Equipped with a Dry Scrubber. Presentation at
the Air & Waste Management Association's 90th Annual Meeting
& Exhibition, June 8-13, 1997.
Visalli, J.R. 1987. A Comparison of Dioxin, Furan and Combustion
Gas Data from Test Programs at Three MSW Incinerators. Haz. Waste
Mang. 37: 1451-1463.
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